| 言語種別 | 日本語 |
|---|---|
| 発行・発表の年月 | 2005 |
| 形態種別 | 学術研究論文 |
| 査読 | 査読あり |
| 標題 | 2色蛍光法による高圧条件下でのpH計測 |
| 執筆形態 | 共著 |
| 掲載誌名 | 日本機械学会論文集 Ｂ編 |
| 掲載区分 | 国内 |
| 出版社・発行元 | 一般社団法人日本機械学会 |
| 巻・号・頁 | 71(704),1161-1168 |
| 担当区分 | 筆頭著者 , 責任著者 |
| 著者・共著者 | 染矢 聡,坂東 茂,西尾 匡弘 |
| 概要 | Any strategy of CO_2 sequestration needs to clear the CO_2 solubility into water and the dissolution behavior. We measured the pH distribution around a dissolving CO_2 droplet in a high pressure vessel by using a 2 color LIF method. Qunine and sulforhodamine were used as fluorescence dyes. Molar absorption coefficient and emission intensity of quinine depends on pH of aqueous solution, while those of sulforhodamine are not affected by pH. The ratio of these fluorescence intensities represents pH at each point of image. The map of pH around the dissolving droplet gives also a map of CO_2 concentration, from which the solubility can be estimated. |
| DOI | 10.1299/kikaib.71.1161 |
| ISSNコード | 0387-5016 |
| NAID(CiNii) | 110005051517 |